94-53-1
- Product Name：Piperonylic acid
- Molecular Formula：C8H6O4
- Purity：99%
- Molecular Weight：166.133
Product Details;
CasNo： 94-53-1
Molecular Formula： C8H6O4
Appearance： white to light yellow crystal powder
Factory Supply Wholesale Piperonylic acid 94-53-1 Best Price
- Molecular Formula:C8H6O4
- Molecular Weight:166.133
- Appearance/Colour:white to light yellow crystal powder
- Vapor Pressure:9.95E-05mmHg at 25°C
- Melting Point:229-231 °C(lit.)
- Refractive Index:1.612
- Boiling Point:324.6 °C at 760 mmHg
- PKA:4.35±0.20(Predicted)
- Flash Point:139.6 °C
- PSA：55.76000
- Density:1.468 g/cm3
- LogP:1.11350
Piperonylic acid(Cas 94-53-1) Usage
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Chemical Properties |
white to light yellow crystal powde |
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Uses |
Piperonylic Acid is a compound closely mimicking the structure of transcinnamic acid involved in the phenylpropanoid pathway in plant physiology. |
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Synthesis Reference(s) |
The Journal of Organic Chemistry, 40, p. 3803, 1975 DOI: 10.1021/jo00913a051 |
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Purification Methods |
Crystallise the acid from EtOH or water. [Beilstein 19/7 V 300.] |
InChI:InChI=1/C8H6O4/c9-8(10)5-1-2-6-7(3-5)12-4-11-6/h1-3H,4H2,(H,9,10)
94-53-1 Relevant articles
Piperonylic Acid, a Selective, Mechanism-Based Inactivator of the trans-Cinnamate 4-Hydroxylase: A New Tool to Control the Flux of Metabolites in the Phenylpropanoid Pathway
Michel Schalk, Francisco Cabello-Hurtado, Marie-Agnès Pierrel, Rossitza Atanassova, Patrick Saindrenan, Danièle Werck-Reichhart
, Plant Physiology, Volume 118, Issue 1, September 1998, Pages 209–218,
Piperonylic acid (PA) is a natural molecule bearing a methylenedioxy function that closely mimics the structure of trans-cinnamic acid. The CYP73A subfamily of plant P450s catalyzes trans-cinnamic acid 4-hydroxylation, the second step of the general phenylpropanoid pathway.
Destructible Surfactants Based on a Silicon-Oxygen Bond
Jaeger, David A.,Ward, Mary Darlene
, p. 2221 - 2223 (1982)
A "destructible" surfactant based on the...
Gram-scale synthesis of carboxylic acids via catalytic acceptorless dehydrogenative coupling of alcohols and hydroxides at an ultralow Ru loading
Chen, Cheng,Cheng, Hua,Verpoort, Francis,Wang, Zhi-Qin,Wu, Zhe,Yuan, Ye,Zheng, Zhong-Hui
, (2021/12/13)
Acceptorless dehydrogenative coupling (A...
Oxidation of Primary Alcohols and Aldehydes to Carboxylic Acids via Hydrogen Atom Transfer
Tan, Wen-Yun,Lu, Yi,Zhao, Jing-Feng,Chen, Wen,Zhang, Hongbin
supporting information, p. 6648 - 6653 (2021/09/08)
The oxidation of primary alcohols and al...
Ni-NiO heterojunctions: a versatile nanocatalyst for regioselective halogenation and oxidative esterification of aromatics
Bhardwaj, Nivedita,Goel, Bharat,Indra, Arindam,Jain, Shreyans K.,Singh, Ajit Kumar,Tripathi, Nancy
, p. 14177 - 14183 (2021/08/16)
Herein, we report a facile method for th...
One-Pot Direct Oxidation of Primary Amines to Carboxylic Acids through Tandem ortho-Naphthoquinone-Catalyzed and TBHP-Promoted Oxidation Sequence
Kim, Hun Young,Oh, Kyungsoo,Si, Tengda
supporting information, p. 18150 - 18155 (2021/12/09)
Biomimetic oxidation of primary amines t...
94-53-1 Process route
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furan-2,3,5(4H)-trione pyridine (1:1)
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piperonal-((E)-O-[1]naphthylcarbamoyl oxime )
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- 94-53-1
Piperonylic acid
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- 607-56-7
1,3-dinaphthalen-1-ylurea
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- 134-32-7
1-amino-naphthalene
| Conditions | Yield |
|---|---|
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O-α-naphthylaminoformyl-β-piperonal oxime;
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- 136-72-1
piperic acid
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- 120-57-0,30024-74-9
piperonal
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- 94-53-1
Piperonylic acid
-
- 133-37-9,138508-61-9
DL-tartaric acid
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- 144-62-7,97993-78-7
oxalic acid
| Conditions | Yield |
|---|---|
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at 3 ℃;
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94-53-1 Upstream products
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109-72-8
n-butyllithium
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2635-13-4
1,2-(methylenedioxy)-4-bromobenzene
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60-29-7
diethyl ether
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120-57-0
piperonal
94-53-1 Downstream products
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326-56-7
methyl 3,4-methylenedioxybenzoate
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6951-08-2
ethyl 1,3-benzodioxole-5-carboxylate
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50-00-0
formaldehyd
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99-50-3
3,4-Dihydroxybenzoic acid
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